A deep-set stain is best removed with oxalic acid (from a hardware store or pharmacy). This chemically combines with the iron and allows it to dissolve. Then wash in soap and water.
Do not use products like CLR or Lime-away as they contain strong mineral acid which will probably react with the cloth.How to wash a cloth with rusted stain?
CLR will work and it won't hurt the material.How to wash a cloth with rusted stain?
SOAK in vinager, or TSP(hardware store)
TSP is better..
Also might try Epson salts..
what these do is loosen the material, so the rust falls out.
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